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Dépôt Institutionnel de l'Université Ferhat ABBAS - Sétif 1 >
Revues Scientifiques >
Verres, Céramiques & Composites >
Volume 4, numéro 01 >
Chemical preparation crystallographic characterization and vibrational study of two new condensed phosphates >
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http://dspace.univ-setif.dz:8888/jspui/handle/123456789/342
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Titre: | Chemical preparation crystallographic characterization and vibrational study of two new condensed phosphates |
Auteur(s): | Tridane, M. Kheireddine, A. Fahim, I. Moutaabbid, H. Moutaabbid, M. EL. M. Tace Charaf, A. Radid, M. Salhamen, F. Benmokhtar, S. Belaaouad, S. |
Mots-clés: | Chemical preparation crystallographic characterization infrared spectrometry NiRb4(P3O9)2, SrTl4(P 3O9) 2 |
Date de publication: | 2015 |
Collection/Numéro: | Volume 4;N°1 |
Résumé: | Chemical preparation, crystallographic characterization and vibrational studies are reported for
two new condensed phosphates associated to nickel-rubidium NiRb4(P3O9)2 and strontium-thallium
SrTl4(P3O9)2. SrTl4(P3O9)2 was prepared by the method of ion-exchange resin and NiRb4(P3O9)2
was
obtained by total thermal dehydration of NiRb4(P3O9)2.6H2O. SrTl4(P3O9)2 is rhombhoedral , Z = 2,
space group P-31c, with the following unit-cell parameters : a = 7,424(1) Å, c = 20,176(2) Å and V =
2807.46(2) (Å
3
). NiRb4(P3O9)2 is triclinic, Z = 2, space group P-1, with the following unit-cell
parameters : a = 8,046(9) Å , b = 9,733(0) Å, c = 4,327(5) Å, α = 98.053°, β = 88.616°, γ = 84.761°
and V = 333,95(2) (Å
3). Vibrational study is also reported for the title compounds. |
URI/URL: | http://dspace.univ-setif.dz:8888/jspui/handle/123456789/342 |
Collection(s) : | Chemical preparation crystallographic characterization and vibrational study of two new condensed phosphates
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