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Volume 4, numéro 01 >
Chemical preparation crystallographic characterization and vibrational study of two new condensed phosphates >

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Titre: Chemical preparation crystallographic characterization and vibrational study of two new condensed phosphates
Auteur(s): Tridane, M.
Kheireddine, A.
Fahim, I.
Moutaabbid, H.
Moutaabbid, M.
EL. M. Tace
Charaf, A.
Radid, M.
Salhamen, F.
Benmokhtar, S.
Belaaouad, S.
Mots-clés: Chemical preparation
crystallographic characterization
infrared spectrometry
NiRb4(P3O9)2, SrTl4(P 3O9) 2
Date de publication: 2015
Collection/Numéro: Volume 4;N°1
Résumé: Chemical preparation, crystallographic characterization and vibrational studies are reported for two new condensed phosphates associated to nickel-rubidium NiRb4(P3O9)2 and strontium-thallium SrTl4(P3O9)2. SrTl4(P3O9)2 was prepared by the method of ion-exchange resin and NiRb4(P3O9)2 was obtained by total thermal dehydration of NiRb4(P3O9)2.6H2O. SrTl4(P3O9)2 is rhombhoedral , Z = 2, space group P-31c, with the following unit-cell parameters : a = 7,424(1) Å, c = 20,176(2) Å and V = 2807.46(2) (Å 3 ). NiRb4(P3O9)2 is triclinic, Z = 2, space group P-1, with the following unit-cell parameters : a = 8,046(9) Å , b = 9,733(0) Å, c = 4,327(5) Å, α = 98.053°, β = 88.616°, γ = 84.761° and V = 333,95(2) (Å 3). Vibrational study is also reported for the title compounds.
URI/URL: http://dspace.univ-setif.dz:8888/jspui/handle/123456789/342
Collection(s) :Chemical preparation crystallographic characterization and vibrational study of two new condensed phosphates

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