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Titre: Electrochemistry of Nanocrystalline La0. 5Sr0. 5MnO3 Perovskite for the Oxygen Reduction Reaction in Alkaline Medium
Auteur(s): Noureddine, Noureddine
Kahoul, Abdelkrim
Naamoune, Farid
Alonso-Vante, Nicolas
Mots-clés: Nanoparticles
Pechini method
Perovskite
Oxygen reduction
Alkaline medium
Date de publication: 8-jan-2019
Collection/Numéro: Electrocatalysis;DOI 10.1007/s12678-017-0397-3
Résumé: Nanocrystalline La0.5Sr0.5MnO3 (LSMO) perovskite-sized powders were successfully synthesized at heating low temperature and time using the Pechini method based on polyesterification between citric acid and ethylene glycol. The electroactivity of carbon-supported perovskite (LSMO/C) for the oxygen reduction reaction (ORR) was evaluated. The results showed that the electroactivity of LSMO/C largely depends on the calcination temperature, type of electrolyte, and mass loading. It increased remarkably with the calcination temperature in 0.1 M KOH. The ORR performance was examined in KOH, NaOH, and K2SO4. Higher electroactivity was recorded in KOH electrolyte, as compared to NaOH and K2SO4.
Description: Published Online: 19 July 2017
URI/URL: http://dspace.univ-setif.dz:8888/jspui/handle/123456789/3056
ISSN: 1868-2529(Print)
1868-5994 (Online)
Collection(s) :Articles

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